Kulinkovich reaction

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English[edit]

Etymology[edit]

Discovered by Oleg Kulinkovich and coworkers in 1989.

Noun[edit]

Kulinkovich reaction (plural Kulinkovich reactions)

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  1. (organic chemistry) The organic synthesis of cyclopropanols via reaction of esters with dialkyldialkoxytitanium reagents, generated in situ from Grignard reagents bearing hydrogen in beta-position and titanium(IV) alkoxides such as titanium isopropoxide.
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